Inclusion of ferrocene in a cyclodextrin-functionalized layered metal hydroxide: A new organometallic-organic-LDH nanohybrid

被引：37
|
作者：
Mohanambe, L [1 ]
Vasudevan, S [1 ]
机构：
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 566012, Karnataka, India
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 07期
关键词：
D O I：
10.1021/ic050039a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cyclodextrin cavities have been grafted into a layered metal hydroxide to create hydrophobic nanopockets within the galleries of the inorganic solid. Neutral ferrocene molecules can be included within the grafted cavities by partitioning from a polar solvent to generate a new organometallic-organic-inorganic hybrid. The included ferrocene has been characterized by electronic and Raman spectroscopy. The capability of the cyclodextrin-functionalized solid to separate hydrophobic and hydrophilic derivatives of ferrocene is demonstrated.
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收藏
页码：2128 / 2130
页数：3
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