A new ligand α-amino acid:: (S)-2-amino-3-[1-(1,4,7-triazacyclononane)]propanoic acid

被引：26
|
作者：
Rossi, P
Felluga, F
Scrimin, P
机构：
[1] Univ Padua, Dept Organ Chem, I-35131 Padua, Italy
[2] CNR, CMRO, I-35131 Padua, Italy
[3] Univ Trieste, Dept Chem Sci, I-34127 Trieste, Italy
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 39期
关键词：
D O I：
10.1016/S0040-4039(98)01532-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The title amino acid was obtained by regiospecific ring-opening reaction of Boc-diprotected 1,4,7-triazacyclononane with (S)-2-beazyloxycarbonylamino-beta-lactone 80% isolated yield) followed by deprotection. It strongly binds transition metal ions like Zn and Cu-II and can be incorporated in peptide sequences without affecting the metal ion affinity of the triazamacrocycle. (C) 1998 Elsevier Science Ltd. All rights reserved.
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收藏
页码：7159 / 7162
页数：4
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