Spectroscopic, Thermal and Structural Studies of Cocrystals of 2,2'-Diamino-4,4'-bis(1,3-thiazole) with 2,5-Bis(4-pyridyl)-3,4-Diaza-2,4-Hexadiene and 1,2-Bis(4-pyridyl)Ethylenediamine

被引:1
|
作者
Abedini, Jafar [2 ]
Safiei, Robabeh [2 ]
Ranjbar, Zohreh Rashidi [1 ]
Morsali, Ali [1 ]
机构
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran
[2] Payame Noor Univ, Dept Chem, Abhar, Zanjan, Iran
关键词
Cocrystal; 2,2 '-Diamino-4,4 '-bis (1,3-thiazole); 2,5-Bis(4-pyridyl)-3,4-diaza-2,4-hexadiene; 1,2-Bis(4-pyridyl)ethylenediamine; CRYSTAL-STRUCTURE; CO-CRYSTAL; COMPLEXES; CADMIUM(II); ACID;
D O I
10.1007/s10870-010-9819-2
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Two cocrystals of 2,2'-diamino-4,4'-bis(1,3-thiazole) (DABTZ) with 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (bpdh) and 1,2-bis(4-pyridyl)ethylenediamine (bpen) {[(DABTZ)(bpdh)] and [(DABTZ)(bpen)], respectively} have been synthesized and characterized by elemental analysis, IR-, H-1 NMR-, C-13 NMR spectroscopy and were studied by thermal analysis and X-ray crystallography. Self-assembly of these compounds in the solid state is likely caused by hydrogen bonding with minor contributions from pi-pi stacking, C-H center dot center dot center dot pi and possibly charge transfer interactions.
引用
收藏
页码:1180 / 1187
页数:8
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