Cobalt-catalyzed asymmetric olefin aziridination with diphenylphosphoryl azide

被引：88
|
作者：
Jones, Jess E.
Ruppel, Joshua V.
Gao, Guang-Yao
Moore, Thomas M.
Zhang, X. Peter [1 ]
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 18期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1021/jo801151x
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cobalt(II) complexes of D(2)-symmetric chiral porphyrins, such as 3,5-Di'Bu-ChenPhyrin P5, can catalyze asymmetric olefin aziridination with dipherylphosphoryl azide (DPPA) as a nitrene source. Acceptable asymmetric inductions were observed for the [Co(P5)]-based catalytic system, forming the desired N-phosphorus-substituted aziridines in moderate to high yields and good enantioselectivities.
引用
收藏
页码：7260 / 7265
页数：6
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