Synthesis of a Redox-Responsive Quadruple Hydrogen-Bonding Unit for Applications in Supramolecular Chemistry

被引：100
|
作者：
Li, Ying [1 ]
Park, Taiho [1 ]
Quansah, J. Kwansima [1 ]
Zimmerman, Steven C. [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 43期
基金：
美国国家科学基金会;
关键词：
BONDED HETEROCOMPLEX; FLAVOENZYME ACTIVITY; DEPENDENT RECEPTORS; MODEL SYSTEMS; RECOGNITION; MICROSPHERES; STABILITY; FIDELITY; BINDING;
D O I：
10.1021/ja2069278
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A redox-responsive quadruple hydrogen-bonding module (eDAN) has been developed. The strong binding between the reduced form and its partner (DeUG) can be significantly decreased upon oxidation but restored upon subsequent reduction. This on-off switch was successfully applied to provide reversible control of macroscopic supramolecular polymer networks.
引用
收藏
页码：17118 / 17121
页数：4
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