Facile one-step electrodeposition preparation of porous NiMo film as electrocatalyst for hydrogen evolution reaction

被引：73
|
作者：
Wang, Mingyong [1 ]
Wang, Zhi [1 ]
Yu, Xiangtao [2 ]
Guo, Zhancheng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
[2] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 05期
关键词：
NiMo film; Electrodeposition; Catalytic activity; Hydrogen evolution reaction; Super gravity field; COPPER; COATINGS; DEPOSITION; CATALYSTS; CATHODES; BEHAVIOR; BUBBLES; CO;
D O I：
10.1016/j.ijhydene.2014.12.022
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Porous NiMo film was prepared by one-step electrodeposition under super gravity field and was used as electrocatalyst for hydrogen evolution reaction (HER). NiMo films possessed three-dimensional porous structure. The thickness of porous layer was up to 180-240 am. Porous NiMo films with extremely large real active area exhibited high catalytic activity for HER. The overpotential was very low and only 47 mV at 100 mA cm(-2). Meanwhile, porous NiMo films possessed good long-term stability by accelerated degradation studies. (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：2173 / 2181
页数：9
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