Synthesis of multiply functionalized benzenes via ruthenium-catalyzed cycloaddition of diiododiynes

被引：32
|
作者：
Yamamoto, Yoshihiko [1 ]
Hattori, Kozo [1 ]
机构：
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
来源：
TETRAHEDRON | 2008年 / 64卷 / 05期
关键词：
D O I：
10.1016/j.tet.2007.09.086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly functionalized benzenes were precisely synthesized via multi-step processes consisting of ruthenium-catalyzed [2+2+2] cycloaddition of diiododiynes with an ethynylboronate or terminal alkynes, and subsequent chemo- and regio-selective palladium-catalyzed C-C bond-forming reactions of the resulting cycloadducts. The sequential cycloaddition/coupling process was applied to the synthesis of oligo(p-phenylene ethynylene)s. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：847 / 855
页数：9
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