Fabrication of polydiacetylene nanowires by associated self-polymerization and self-assembly processes for efficient field emission properties

被引:358
|
作者
Gan, HY
Liu, HB
Li, YJ
Zhao, Q
Li, YL [1 ]
Wang, S
Jiu, TG
Wang, N
He, XR
Yu, DP
Zhu, DB
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China
[2] Peking Univ, Dept Phys, Beijing 100871, Peoples R China
关键词
D O I
10.1021/ja053352k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The paper described here concerns a challenge of general interest for producing a novel structure of a polymer aggregate, the achievement of nanowires with controlled diameters. We provide a strategy for fabricating a supramolecular polymer, in which ordered polydiacetylene nanowires can be obtained by associated self-polymerization and self-assembly processes. The polymer nanowire film shows excellent field emission properties with the turn-on field of 8.2 V/μm at 10 μA/cm2 and the maximum current density of 5 mA/cm2 at an applied field of 15 V/μm. Copyright © 2005 American Chemical Society.
引用
收藏
页码:12452 / 12453
页数:2
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