Carbazole- and thiophene-containing conjugated microporous polymers with different planarity for enhanced photocatalytic hydrogen evolution

被引:40
|
作者
Lee, Tsung-Lin [1 ]
Elewa, Ahmed M. [2 ]
Kotp, Mohammed G. [1 ]
Chou, Ho-Hsiu [2 ]
EL-Mahdy, Ahmed F. M. [1 ]
机构
[1] Natl Sun Yat Sen Univ, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan
[2] Natl Tsing Hua Univ, Dept Chem Engn, 101,Sec 2,Kuang Fu Rd, Hsinchu 30013, Taiwan
关键词
ORGANIC PHOTOCATALYSTS; FRAMEWORKS;
D O I
10.1039/d1cc04551b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis of two carbazole-thiophene-based conjugated microporous polymers (Cz-3Th and Cz-4Th CMPs) with different degrees of planarity for photocatalytic hydrogen evolution from water. Depending upon the building linker's planarity, we found that the porous structure, hydrogen-evolution rate, and photocatalytic stability of the resultant CMPs varied.
引用
收藏
页码:11968 / 11971
页数:4
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