Bis(piperazinium) di-μ-chloro-bis[tetrachlorobismuthate(III)] trihydrate

被引:6
|
作者
Wu, PF [1 ]
Tan, XF
Meng, XG
Li, DS
Zhu, YL
Wei, YG
机构
[1] Hubei Univ Technol, Coll Bioengn, Dept Food Sci, Wuhan 430068, Peoples R China
[2] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China
[3] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
D O I
10.1107/S1600536805021100
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title salt, (C4H12N2)(2)[Bi2Cl10]center dot 3H(2)O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi2Cl10](4-) tetraanions, the latter with twofold rotation symmetry, together with water of crystallization. Hydrogen-bond interactions, including N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl interactions, stabilize the crystal structure.
引用
收藏
页码:M1506 / M1508
页数:3
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