A fluidized bed reactor as an approach to enzymatic biodiesel production in a process with simultaneous glycerol removal

被引：30
|
作者：
Fidalgo, Weriton R. R. [1 ]
Ceron, Annie [1 ]
Freitas, Larissa [1 ]
Santos, Julio C. [1 ]
de Castro, Heizir F. [1 ]
机构：
[1] Univ Sao Paulo, Engn Sch Lorena, BR-12602810 Lorena, SP, Brazil
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2016年 / 38卷
基金：
巴西圣保罗研究基金会;
关键词：
Biodiesel; Fluidized bed reactor; Glycerol removal; Solvent-free system; Novozym (R) 435; Lewatit (R) GF202; IMMOBILIZED LIPASE; ETHANOLYSIS; BABASSU; OIL;
D O I：
10.1016/j.jiec.2016.05.005
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrodynamic characteristics and operational conditions to produce biodiesel by the ethanolysis of babassu oil catalyzed by immobilized lipase (Novozym (R) 435) were established in a fluidized bed reactor coupling with a column to simultaneous remove glycerol formed as byproduct. Hydrodynamics was determined by means of pulse tracer trials and results showed that the flow pattern can be described as an ideal continuous flow stirred tank. The best performance was obtained by running the reactor with biocatalyst loading of 12% and a space-time of 8 h, attaining an average yield of 98.1% and productivity of 9.9 mol(ester)/g(cat)/min. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：217 / 223
页数：7
相关论文
共 50 条
  • [1] Process engineering and optimization of glycerol separation in a packed-bed reactor for enzymatic biodiesel production
    Hama, Shinji
    Tamalampudi, Sriappareddy
    Yoshida, Ayumi
    Tamadani, Naoki
    Kuratani, Nobuyuki
    Noda, Hideo
    Fukuda, Hideki
    Kondo, Akihiko
    BIORESOURCE TECHNOLOGY, 2011, 102 (22) : 10419 - 10424
  • [2] Simultaneous removal of phenol and nitrate in an anoxic fluidized bed reactor
    Omena, Sylvia P. F.
    Sader, Leandro T.
    Silva, Edson L.
    JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2013, 48 (05): : 581 - 591
  • [3] A CFD approach on simulation of hydrogen production from steam reforming of glycerol in a fluidized bed reactor
    Dou, Binlin
    Song, Yongchen
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (19) : 10271 - 10284
  • [4] Simulation of Process Interesterification in Fluidized Bed Bioreactor for Production of Biodiesel
    Mendes, Jocelia S.
    Silva, Jouciane S.
    Ferreira, Andrea L. O.
    Silva, Giovanilton F.
    10TH INTERNATIONAL SYMPOSIUM ON PROCESS SYSTEMS ENGINEERING, 2009, 27 : 1803 - 1808
  • [5] Simultaneous removal of carbon and nitrogen in an anaerobic inverse fluidized bed reactor
    Alvarado-Lassman, A.
    Rustrian, E.
    Garcia-Alvarado, M. A.
    Houbron, E.
    WATER SCIENCE AND TECHNOLOGY, 2006, 54 (02) : 111 - 117
  • [6] Fluidized bed reactor for fluoride removal
    Aldaco, R
    Irabien, A
    Luis, P
    CHEMICAL ENGINEERING JOURNAL, 2005, 107 (1-3) : 113 - 117
  • [7] Fluidized bed reactor for fluoride removal
    Aldaco, R.
    Irabien, A.
    Luis, P.
    Chemical Engineering Journal, 2005, 107 (1-3): : 113 - 117
  • [8] Removal and recovery of lead in a fluidized-bed reactor by crystallization process
    de Luna, Mark Daniel G.
    Bellotindos, Luzvisminda M.
    Asiao, Rino N.
    Lu, Ming-Chun
    HYDROMETALLURGY, 2015, 155 : 6 - 12
  • [9] Utilization of fluidized bed reactor for the production of adsorbents in removal of malachite green
    Rajgopal, S
    Karthikeyan, T
    Kumar, BGP
    Miranda, LR
    CHEMICAL ENGINEERING JOURNAL, 2006, 116 (03) : 211 - 217
  • [10] Enzymatic packed-bed reactor integrated with glycerol-separating system for solvent-free production of biodiesel fuel
    Hama, Shinji
    Tamalampudi, Sriappareddy
    Yoshida, Ayumi
    Tamadani, Naoki
    Kuratani, Nobuyuki
    Noda, Hideo
    Fukuda, Hideki
    Kondo, Akihiko
    BIOCHEMICAL ENGINEERING JOURNAL, 2011, 55 (01) : 66 - 71
12345