Reactivity of Cu(I) nacnac complexes towards [Cp*Ru(η5-E5)] (E = P, As)

被引：0
|
作者：
Haimerl, Maria [1 ]
Scheer, Manfred [1 ]
机构：
[1] Univ Regensburg, Inst Inorgan Chem, Univ Str 31, D-93040 Regensburg, Germany
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2022年 / 197卷 / 5-6期
关键词：
cyclo-E-n ligands; coordination; copper; ruthenium; nacnac; heterometallic complexes; BOND COVALENT RADII; NICKEL-COMPLEXES; P-4; ACTIVATION; PENTAPHOSPHAFERROCENE; LIGAND; PHOSPHORUS; ELEMENTS; CHEMISTRY; IRON;
D O I：
10.1080/10426507.2021.2011888
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactivity of the nacnac Cu(I) compound [(LCu)-Cu-2(MeCN)] (2) (L-2 = [{N(C6H3Me2-2,6)C(Me)}(2)CH](-)) towards complexes containing aromatic cyclo-E-5 ligands (E = P, As) was investigated. The copper complex was reacted with [Cp*Ru(eta(5)-E-5)] (E = P (1a-Ru), As (1b-Ru)), yielding the heterometallic complexes [(Cp*Ru)(mu,eta(5:2)-E-5)((LCu)-Cu-2)] (E = P (3a), As (3b)). These neutral and molecular complexes represent rare examples of the coordination of group 11 metal complexes to cyclo-E-n units and are also rare examples of the coordination compounds of 1a-Ru and 1b-Ru. They were fully characterized by crystallographic and spectroscopic methods and compared to related compounds.
引用
收藏
页码：393 / 397
页数：5
相关论文
共 50 条
  • [1] Structures and bonding of the complexes [M(η5-E5)] and [M(η5-E5)2] (M = Sc, Y, E = N, P): a DFT study
    Kai-Sheng Diao
    Hai-Jun Wang
    Qing-Yu Ge
    [J]. Structural Chemistry, 2007, 18 : 875 - 882
  • [2] Structures and bonding of the complexes [M(η5-E5)] and [M(η5-E5)2] (M = Sc, Y, E = N, P):: a DFT study
    Diao, Kai-Sheng
    Wang, Hai-Jun
    Ge, Qing-Yu
    [J]. STRUCTURAL CHEMISTRY, 2007, 18 (06) : 875 - 882
  • [3] Reactivity of the pentelidene complexes [Cp*E{W(CO)5}2] (E = P, As) towards dichalcogenides and chalcogenols - synthesis of novel chalcogenopentelidene complexes
    Rummel, Lena
    Lassandro, Giuliano
    Seidl, Michael
    Timoshkin, Alexey Y.
    Scheer, Manfred
    [J]. DALTON TRANSACTIONS, 2021, 50 (36) : 12648 - 12654
  • [4] Structures and bonding of the sandwich complexes [Ti(η5-E5)2]2- (E = CH, N, P, As, Sb):: A theoretical study
    Lein, M
    Frunzke, J
    Frenking, G
    [J]. INORGANIC CHEMISTRY, 2003, 42 (08) : 2504 - 2511
  • [5] Reactivity of Cu(I) Nacnac Complexes Toward Polypnictogen Compounds
    Haimerl, Maria
    Piesch, Martin
    Balazs, Gabor
    Mastrorilli, Piero
    Kremer, Werner
    Scheer, Manfred
    [J]. INORGANIC CHEMISTRY, 2021, 60 (08) : 5840 - 5850
  • [6] Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) - unprecedented structural motifs of the resulting polypnictogen ligands
    Dinauer, Sabrina B.
    Szlosek, Robert
    Piesch, Martin
    Balazs, Gabor
    Reichl, Stephan
    Prock, Lukas
    Riesinger, Christoph
    Walter, Marc D.
    Scheer, Manfred
    [J]. DALTON TRANSACTIONS, 2024, 53 (24) : 10201 - 10207
  • [7] Structures, metal-ligand bond strenght, and bonding analysis of ferrocene derivatives with group-15 heteroligands Fe(η5-E5)2 and FeCp(η5-E5) (E = N, P, As, Sb).: A theoretical study
    Frunzke, J
    Lein, M
    Frenking, G
    [J]. ORGANOMETALLICS, 2002, 21 (16) : 3351 - 3359
  • [8] Electride characteristics of M2(η5-E5)2 (M = Be, Mg; E = Sb5-)
    Prasenjit Das
    Pratim Kumar Chattaraj
    [J]. Structural Chemistry, 2021, 32 : 2107 - 2114
  • [9] Reactivity of Cp*Co(I) equivalents towards E-E (E = N, O, and S) bonds
    Dalphon, Katelyn
    Bradley, Christopher
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [10] Electride characteristics of M2(η5-E5)2 (M = Be, Mg; E = Sb5-)
    Das, Prasenjit
    Chattaraj, Pratim Kumar
    [J]. STRUCTURAL CHEMISTRY, 2021, 32 (06) : 2107 - 2114
12345