Glassy relaxation and excess wing in mode-coupling theory: The dynamic susceptibility of propylene carbonate above and below Tc

被引:25
|
作者
Domschke, Markus [1 ]
Marsilius, Mie [1 ]
Blochowicz, Thomas [1 ]
Voigtmann, Thomas [2 ,3 ]
机构
[1] Tech Univ Darmstadt, Inst Festkorperphys, D-64289 Darmstadt, Germany
[2] Deutsch Zentrum Luft & Raumfahrt DLR, Inst Mat Phys Weltraum, D-51170 Cologne, Germany
[3] Univ Konstanz, Zukunftskolleg & Fachbereich Phys, D-78457 Constance, Germany
来源
PHYSICAL REVIEW E | 2011年 / 84卷 / 03期
关键词
LIGHT-SCATTERING; SUPERCOOLED LIQUIDS; NONUNIVERSAL FEATURES; SECONDARY RELAXATIONS; DIELECTRIC RESPONSE; FORMING LIQUIDS; TRANSITION; SPECTROSCOPY; UNIVERSAL; EVOLUTION;
D O I
10.1103/PhysRevE.84.031506
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We explore the possibility of describing experimental susceptibility spectra of the glass former propylene carbonate with a two-component schematic model of mode-coupling theory (MCT) from above the melting point down to temperatures far below the critical temperature of MCT. By introducing a phenomenological time-dependent hopping rate, the spectra are reproduced in the full frequency and temperature range available. Literature data of dielectric susceptibilities and depolarized Brillouin light-scattering spectra are combined with our measurements of photon correlation spectroscopy to cover up to 18 decades in frequency of spectra for two different dynamical variables. A consistent description of all data sets is obtained by adjusting only a few physically motivated parameters. In particular the excess wing or slow beta-relaxation commonly observed in the susceptibility spectra can consistently be modeled as originating from a coupling of the individual experimental probe correlator to the collective density fluctuations.
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页数:12
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