Hydrostatic Pressure-Controllable Chiroptical Properties of Chiral Perylene Bisimide Dyes: A Chiral Aggregation Case

被引：4
|
作者：
Kinoshita, Tomokazu [1 ]
Imai, Yoshitane [2 ]
Fukuhara, Gaku [1 ,3 ]
机构：
[1] Tokyo Inst Technol, Dept Chem, Tokyo 1528551, Japan
[2] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
[3] JST, PRESTO, Kawaguchi, Saitama 3320012, Japan
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2021年 / 125卷 / 22期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
ENHANCED DIASTEREOSELECTIVITY; ALPHA-CYCLODEXTRIN; LOW-TEMPERATURE; LUMINESCENCE; MOLECULES; PHOTOISOMERIZATION; AMPLIFICATION; FLUORESCENCE; DERIVATIVES; SWITCHES;
D O I：
10.1021/acs.jpcb.1c02112
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrostatically pressurized spectroscopic and lifetime decay analyses of optically active perylene bisimides were demonstrated in the pressure range of 0.1-320 MPa to show a pi-stacked aggregation. The hydrostatic pressure-induced excitation and circular dichroism spectral changes of the fluorescence perylene dye enabled us to differentiate the slight pressure-sensitive aggregates. This work will lead to a new strategy for creating a pressure-responsive supramolecular polymerization material.
引用
收藏
页码：5952 / 5958
页数：7
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