Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl]2[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime

被引：0

作者：

Larionov, SV

Savel'eva, ZA

Glinskaya, LA

Klevtsova, RF

Ikorskii, VN

Bizyaev, SN

Tkachev, AV

机构：

[1] Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new paramagnetic compound [Cu(HL)Cl](2)[CuCl4], where HL is optically active (1S,3S,6R)-3-[N-(3-aminopropyl)amino]-4-caranone (E)-oxime, was synthesized. Its crystal and molecular structure was determined by X-ray diffraction. The compound consists of complex cations [Cu(HL)Cl](+) and outer-sphere tetrahedral anions [CuCl4](2-). In the complex cation, the Cu2+, ion coordinates three N atoms (Cu-N 1.967(5)-2.029(5) A) of the tridentate ring-forming ligand HL and one Cl atom (Cu-Cl 2.281(2) angstrom). The coordination core CuN3Cl is a distorted square.

引用

页码：711 / 714

页数：4

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