Thermal and FTIR spectroscopic analysis of the interactions of aniline adsorbed on to MCM-41 mesoporous material

被引：31
|
作者：
Eimer, GA [1 ]
Costa, MBG [1 ]
Pierella, LB [1 ]
Anunziata, OA [1 ]
机构：
[1] Natl Univ Cordoba, Fac Reg Cordoba, Grp Fisicoquim Nuevos Mat, CITeQ, RA-5016 Cordoba, Argentina
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2003年 / 263卷 / 02期
关键词：
aniline; adsorption; MCM-41; mesoporous materials; nanomaterials; FT-IR spectroscopy; thermal analysis;
D O I：
10.1016/S0021-9797(03)00038-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The adsorption of aniline on Na-AlMCM-41 synthesized by us has been characterized by infrared spectroscopy, temperature programmed desorption (TPD), and differential thermal analysis methods. Aniline would be mostly bound to the mesostructure through weak pi interactions. On the mesostructure containing adsorbed water, the co-adsorption of aniline could occur by weak hydrogen bonding through surface water molecules. For water, two possible modes of adsorption have been identified. Different associations between aniline and hydrated and nonhydrated mesostructures have been evaluated in order to favor the posterior in situ polymerization of adsorbed aniline. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码：400 / 407
页数：8
相关论文
共 50 条
  • [1] Thermal conductivity of mesoporous material MCM-41
    Huang Cong-Liang
    Feng Yan-Hui
    Zhang Xin-Xin
    Wang Ge
    Li Jing
    ACTA PHYSICA SINICA, 2011, 60 (11)
  • [2] Characterization of Cu/MCM-41 and Cu/MCM-48 mesoporous catalysts by FTIR spectroscopy of adsorbed CO
    Hadjiivanov, K
    Tsoncheva, T
    Dimitrov, M
    Minchev, C
    Knözinger, H
    APPLIED CATALYSIS A-GENERAL, 2003, 241 (1-2) : 331 - 340
  • [3] Diffusion of alcohols and aromatics in a mesoporous MCM-41 material
    Ergun, Asli Nalbant
    Kocabas, Zuleyha Ozlem
    Yurum, Alp
    Yurum, Yuda
    FLUID PHASE EQUILIBRIA, 2014, 382 : 169 - 179
  • [4] FTIR AND NMR STUDIES OF ADSORBED CETHYLTRIMETHYLAMMONIUM CHLORIDE IN MCM-41 MATERIALS
    Taba, Paulina
    Howe, Russell F.
    Moran, Graine
    INDONESIAN JOURNAL OF CHEMISTRY, 2008, 8 (01) : 1 - 6
  • [5] In situ FTIR study of the thermal treatment on boron containing mesoporous molecular sieve MCM-41
    Zhang, C
    Wang, YL
    Xie, ZE
    Guan, N
    Liu, S
    Luan, Z
    Klinowski, J
    RECENT ADVANCES IN THE SCIENCE AND TECHNOLOGY OF ZEOLITES AND RELATED MATERIALS, PTS A - C, 2004, 154 : 1485 - 1489
  • [6] Synthesis of PPFBS Modified MCM-41 Mesoporous Material and Its Thermal Decomposition Property
    Han Zhidong
    Wang Yongliang
    Dong Liming
    Xu Feng
    Hu Yuanwei
    Li Baoqiang
    RARE METAL MATERIALS AND ENGINEERING, 2013, 42 : 785 - 788
  • [7] Cumene cracking on modified mesoporous material type MCM-41
    Belhakem, Ahmed
    Bengueddach, Abdelkader
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2006, 20 (01) : 89 - 97
  • [8] Synthesis of MCM-41 Mesoporous Material in an Open Reaction System
    Zhang Aiju
    Li Zhihong
    Li Zicheng
    Shen Yi
    Zhu Yumei
    RARE METAL MATERIALS AND ENGINEERING, 2008, 37 : 671 - 673
  • [9] Mesoporous MCM-41 material for hydrogen storage: A short review
    Dundar-Tekkaya, Ezgi
    Yurum, Yuda
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (23) : 9789 - 9795
  • [10] Cumene cracking on modified mesoporous material type MCM-41
    Belhakem, Ahmed
    Bengueddach, Abdelkader
    TURKISH JOURNAL OF CHEMISTRY, 2006, 30 (03) : 287 - 295
12345