Synthesis of three-arm star block copolymers

被引:0
|
作者
Lambert, O [1 ]
Reutenauer, S [1 ]
Hurtrez, G [1 ]
Dumas, P [1 ]
机构
[1] Univ Haute Alsace, CNRS, Ecole Natl Super Chim, Lab Chim Macromol, F-68093 Mulhouse, France
关键词
D O I
10.1002/1521-3900(200010)161:1<97::AID-MASY97>3.0.CO;2-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We describe the synthesis and characterization of three-arm star block copolymers based on polystyrene, poly(ethylene oxide), poly(epsilon -caprolactone), poly(methyl methacrylate), poly(tert-butyl methacrylate) and poly(L-lactide) blocks. The copolymers were obtained by a route consisting of two successive initiation steps on functional macroinitiator. Some results on micellization and crystallization are given. They indicate an increase in the miscibility of different incompatible blocks.
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页码:97 / 102
页数:6
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