Incorporation of Fe3O4 nanoparticles in three-dimensional carbon nanofiber/carbon nanotube aerogels for high-performance anodes of lithium-ion batteries

被引:7
|
作者
Chen, Jisi [1 ]
Chen, Yu [1 ]
Li, Chen [1 ]
Hu, Yang [1 ]
Fang, Lingxiao [1 ]
Yang, Quanling [1 ]
Shi, Zhuqun [1 ,2 ]
Xiong, Chuanxi [1 ]
机构
[1] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
[2] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Peoples R China
关键词
carbon nanotubes; carbon nanofibers; Fe3O4 composite aerogels; 3-dimensional network; ENERGY-STORAGE; NANOCOMPOSITES; NANOSPHERES; COMPOSITE; CAPACITY; GRAPHENE;
D O I
10.1016/j.colsurfa.2021.127716
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, Fe3O4 based materials have been widely investigated to serve as anode materials of lithium-ion batteries (LIBs) because of the high theoretical capacity (924 mA h g(-1)). Unfortunately, the actual capacity of these materials are low and they suffer from poor cycling stability. Herein, carbon nanotube/carbon nanofiber composite aerogels (CA) were used as scaffold to fabricate Fe3O4-CA composites for anode materials. Fe3O4 nanoparticles were evenly presented on the external surface and internal channel of the 3-dimensional (3D) CA network. The 3D conductive network can buffer the volume expansion of anode materials. Additionally, such structure can prevent the aggregation of Fe3O4. Therefore, the structure of the Fe3O4-CA composite electrode can be maintained during lithiation/delithiation processes. The Fe3O4-CA composites delivered a high reversible capacity of 825.1 mA h g(-1) after 100 cycles. Additionally, an ultra-high coulombic efficiency closed to 100% was obtained. The excellent performance of the Fe3O4-CA composites may be due to the synergistic effect of the Fe3O4 nanoparticles and 3D conductive network structure.
引用
收藏
页数:7
相关论文
共 50 条
  • [1] Anchoring Fe3O4 nanoparticles on three-dimensional carbon nanofibers toward flexible high-performance anodes for lithium-ion batteries
    Wan, Yizao
    Yang, Zhiwei
    Xiong, Guangyao
    Guo, Ruisong
    Liu, Ze
    Luo, Honglin
    [J]. JOURNAL OF POWER SOURCES, 2015, 294 : 414 - 419
  • [2] Three-Dimensional ZnMn2O4 Nanoparticles/Carbon Cloth Anodes for High-Performance Flexible Lithium-Ion Batteries
    Dong, Liang
    Hao, Jin
    Liu, Huiyin
    Shi, Wenhui
    Yang, Jialin
    Lian, Jianshe
    [J]. CHEMISTRYSELECT, 2020, 5 (08): : 2372 - 2378
  • [3] Conformal Fe3O4 Sheath on Aligned Carbon Nanotube Scaffolds as High-Performance Anodes for Lithium Ion Batteries
    Wu, Yang
    Wei, Yang
    Wang, Jiaping
    Jiang, Kaili
    Fan, Shoushan
    [J]. NANO LETTERS, 2013, 13 (02) : 818 - 823
  • [4] Fe3O4 nanoparticle decorated three-dimensional porous carbon/MoS2 composites as anodes for high performance lithium-ion batteries
    Jeon, Youngmoo
    Lee, Jeongyeon
    Kim, Myungjin
    Oh, Jiseop
    Hwang, Taejin
    Piao, Yuanzhe
    [J]. NANOSCALE, 2019, 11 (11) : 4837 - 4845
  • [5] Three-Dimensional Porous Carbon-Silicon Frameworks as High-Performance Anodes for Lithium-Ion Batteries
    Wang, Ming-Shan
    Song, Yu
    Song, Wei-Li
    Fan, Li-Zhen
    [J]. CHEMELECTROCHEM, 2014, 1 (12): : 2124 - 2130
  • [6] CoFe2O4/carbon nanotube aerogels as high performance anodes for lithium ion batteries
    Xin Sun
    Xiaoyi Zhu
    Xianfeng Yang
    Jin Sun
    Yanzhi Xia
    Dongjiang Yang
    [J]. Green Energy & Environment, 2017, 2 (02) : 160 - 167
  • [7] CoFe2O4/carbon nanotube aerogels as high performance anodes for lithium ion batteries
    Sun, Xin
    Zhu, Xiaoyi
    Yang, Xianfeng
    Sun, Jin
    Xia, Yanzhi
    Yang, Dongjiang
    [J]. GREEN ENERGY & ENVIRONMENT, 2017, 2 (02) : 160 - 167
  • [8] Structure and electrochemical performance of nanostructured Fe3O4/carbon nanotube composites as anodes for lithium ion batteries
    He, Yang
    Huang, Ling
    Cai, Jin-Shu
    Zheng, Xiao-Mei
    Sun, Shi-Gang
    [J]. ELECTROCHIMICA ACTA, 2010, 55 (03) : 1140 - 1144
  • [9] Fe3O4 nanoflakes in an N-doped carbon matrix as high-performance anodes for lithium ion batteries
    Guo, Cong
    Wang, Lili
    Zhu, Yongchun
    Wang, Danfeng
    Yang, Qianqian
    Qian, Yitai
    [J]. NANOSCALE, 2015, 7 (22) : 10123 - 10129
  • [10] Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries
    Hao, Shiji
    Zhang, Bowei
    Wang, Ying
    Li, Chaojiang
    Feng, Jianyong
    Ball, Sarah
    Srinivasan, Madhavi
    Wu, Junsheng
    Huang, Yizhong
    [J]. ELECTROCHIMICA ACTA, 2018, 260 : 965 - 973