Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate

被引：853
|
作者：
Swatloski, RP
Holbrey, JD
Rogers, RD
机构：
[1] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
来源：
GREEN CHEMISTRY | 2003年 / 5卷 / 04期
关键词：
D O I：
10.1039/b304400a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1-Butyl-3-methylimidazolium fluoride hydrate has been identified crystallographically as a decomposition product created during purification of the hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. This highlights the need to treat ionic liquids much as one would any other research chemical with potentially hazardous properties, unknown toxicity and/or stability, particularly when searching for 'green solvents'.
引用
收藏
页码：361 / 363
页数：3
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