Progress on Selective Catalytic Ammonia Oxidation (NH3-SCO) over Cu-Containing Zeolite-Based Catalysts

被引:41
|
作者
Jablonska, Magdalena [1 ]
机构
[1] Univ Leipzig, Inst Chem Technol, Linnestr 3, D-04103 Leipzig, Germany
关键词
ammonia; selective catalytic oxidation; chabazite; copper; mechanisms; NH3; OXIDATION; NOX REDUCTION; CU/SAPO-34; CATALYSTS; SLIP AMMONIA; NITROGEN; PERFORMANCE; CU-SSZ-13; MECHANISM; SITES; CU/SSZ-13;
D O I
10.1002/cctc.202000649
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The selective catalytic oxidation of ammonia into nitrogen and water vapor (NH3-SCO) has proven to be the most efficient technique for the removal of NH(3)from the oxygen-containing diesel exhausts. Until now, two reviews over investigated catalysts have been published in 2015-2016 (Jablonska et al., RCS. Adv. 2015; Appl. Catal. B: Environ. 2016). Among various NH3-SCO catalysts, Cu- and/or Fe-containing zeolites are considered as promising candidates due to their benign nature, NH(3)storage capacity, very high NH(3)conversion and N(2)selectivity. The present review focusses only on the Cu-containing zeolites (mainly on chabazite (CHA): SSZ-13, SAPO-34) catalysts) applied in NH3-SCO starting from 2015. The synthesis/preparation methods and the state of Cu in catalysts on the activity and selectivity are highlighted. The advantages of the understanding of the reaction mechanism are reviewed. Finally, an outlook is given together with expected inspirations for future research directions in developing zeolite-based catalysts.
引用
收藏
页码:4490 / 4500
页数:11
相关论文
共 50 条
  • [1] Progress on selective catalytic oxidation of ammonia (NH3-SCO) over Ag-based catalysts
    Wang, Fei
    Li, Zhao
    Wang, Chunxue
    Xu, Guangyan
    Chu, Biwu
    Zhang, Changbin
    He, Hong
    [J]. CATALYSIS TODAY, 2023, 423
  • [2] Progress on Noble Metal-Based Catalysts Dedicated to the Selective Catalytic Ammonia Oxidation into Nitrogen and Water Vapor (NH3-SCO)
    Jablonska, Magdalena
    [J]. MOLECULES, 2021, 26 (21):
  • [3] Cu-Mg-Fe-O-(Ce) Complex Oxides as Catalysts of Selective Catalytic Oxidation of Ammonia to Dinitrogen (NH3-SCO)
    Gorecka, Sylwia
    Pacultova, Katerina
    Gorecki, Kamil
    Smykalova, Aneta
    Pamin, Katarzyna
    Obalova, Lucie
    [J]. CATALYSTS, 2020, 10 (02)
  • [4] Role of the support on the behavior of Ag-based catalysts for NH3 selective catalytic oxidation (NH3-SCO)
    Qu, Zhenping
    Wang, Hui
    Wang, Shudong
    Cheng, Hao
    Qin, Yuan
    Wang, Zhong
    [J]. APPLIED SURFACE SCIENCE, 2014, 316 : 373 - 379
  • [5] Advances in selective catalytic oxidation of ammonia (NH3-SCO) to dinitrogen in excess oxygen: A review on typical catalysts, catalytic performances and reaction mechanisms
    Gao, Fengyu
    Liu, Yuanyuan
    Sani, Zaharaddeen
    Tang, Xiaolong
    Yi, Honghong
    Zhao, Shunzheng
    Yu, Qingjun
    Zhou, Yuansong
    [J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (01):
  • [6] Comparison of Cu-Mg-Al-Ox and Cu/Al2O3 in selective catalytic oxidation of ammonia (NH3-SCO)
    Jablonska, Magdalena
    Wolkenar, Bernd
    Beale, Andrew M.
    Pischinger, Stefan
    Palkovits, Regina
    [J]. CATALYSIS COMMUNICATIONS, 2018, 110 : 5 - 9
  • [7] Review of the application of Cu-containing SSZ-13 in NH3-SCR-DeNOx and NH3-SCO
    Jablonska, Magdalena
    [J]. RSC ADVANCES, 2022, 12 (39) : 25240 - 25261
  • [8] Nature of Cu active sites in zeolite-based catalysts for selective catalytic oxidation of methane
    Sun, Han
    Liu, Chuntong
    Chen, Haijun
    [J]. RESEARCH ON CHEMICAL INTERMEDIATES, 2019, 45 (12) : 5849 - 5861
  • [9] Nature of Cu active sites in zeolite-based catalysts for selective catalytic oxidation of methane
    Han Sun
    Chuntong Liu
    Haijun Chen
    [J]. Research on Chemical Intermediates, 2019, 45 : 5849 - 5861
  • [10] A Comparative Mini-Review on Transition Metal Oxides Applied for the Selective Catalytic Ammonia Oxidation (NH3-SCO)
    Jablonska, Magdalena
    Robles, Alejandro Molla
    [J]. MATERIALS, 2022, 15 (14)