The Effect of Electrode Thickness on the High-Current Discharge and Long-Term Cycle Performance of a Lithium-Ion Battery

被引:10
|
作者
Li, Dongjian [1 ]
Lv, Qiqi [2 ]
Zhang, Chunmei [3 ]
Zhou, Wei [4 ]
Guo, Hongtao [2 ]
Jiang, Shaohua [2 ]
Li, Zhuan [1 ]
机构
[1] Cent South Univ, Natl Key Lab Sci & Technol High Strength Struct M, Changsha 410083, Peoples R China
[2] Nanjing Forestry Univ, Coll Mat Sci & Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China
[3] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Inst Mat Sci & Devices, Suzhou 215009, Peoples R China
[4] Hunan Univ Technol, Coll Met & Mat Engn, Zhuzhou 412007, Peoples R China
来源
BATTERIES-BASEL | 2022年 / 8卷 / 08期
基金
中国国家自然科学基金;
关键词
electrode thickness; lithium-ion battery; impedance; power performance; cycle life; NI-RICH; ELECTROCHEMICAL PERFORMANCE; CATHODE MATERIALS; DIFFUSION; MORPHOLOGY; CELLS;
D O I
10.3390/batteries8080101
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Six groups of electrodes with different thickness are prepared in the current study by using Li[Ni1/3Co1/3MN1/3]O-2 as the active substance; the electrode thicknesses are 71.8, 65.4, 52.6, 39.3, 32.9, and 26.2 mu m, respectively, with similar internal microstructures. The effect of electrode thickness on the discharge rate, pulse discharge, internal resistance, and long-term cycle life of a pouch cell are investigated. The results show that, with the decrease in the electrode thickness from 71.8 mu m to 26.2 mu m, the high-current-discharge performance of the cell gradually improves, the pulse-discharge power density under 50% SOC increases from 1561 W/Kg to 2691 W/Kg, the R-dis decreases from 8.70 m omega to 3.34 m omega, and the internal resistance decreases from 3.36 m omega to 1.21 m omega. In the long-term cycle-life test, the thinner the electrode thickness, the less the capacity fading of the cell; the internal resistance of the cell is observed with the increase in the cycle index.
引用
收藏
页数:13
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