The Effect of Hyperbranched Polyester Epoxy Resin on the Curing Kinetics and Thermal Degradation Kinetics of the Diglycidyl Ether of Bisphenol-A Epoxy Resin

被引：9

作者：

Zhang, Daohong ^{[1
,3
]}

Chen, Sufang ^{[2
]}

Zhou, Jiliang ^{[1
]}

Li, Tingcheng ^{[1
]}

Zhang, Aiqing ^{[1
]}

机构：

[1] S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei Province, Peoples R China

[2] Wuhan Inst Technol, Key Lab Green Chem Proc, Minist Educ, Wuhan, Hubei, Peoples R China

[3] Wujiang Taihu Insulating Mat Co Ltd, Suzhou, Jiangsu, Peoples R China

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2010年 / 49卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Curing; Hyperbranched epoxy resin; Kinetics; Thermal degradation; THERMOGRAVIMETRIC DATA; TOUGHNESS; POLYMERS; PERFORMANCE; BLENDS; SYSTEM;

D O I：

10.1080/03602559.2010.496406

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hyperbranched poly(trimellitic anhydride butylene glycol)ester epoxy (HTBE) has relatively low viscosity and high molecular mass and holds great promise as a functional additive for enhancing the strength and toughness of thermosetting resins. The effect of molecular mass or generation and content of HTBE on the activation energy, reaction order, and curing time was discussed using DSC and TG techniques. The results indicated that HTBE could accelerate the curing speed and reduce the activation energy and reaction order of the curing reaction, and the thermal degradation activation energy (Ea2) of HTBE/DGEBA hybrid resin also decreased remarkably in high temperature section.

引用

页码：1182 / 1187

页数：6

共 50 条

[1] Kinetics of curing and thermal degradation of hyperbranched epoxy (HTDE)/diglycidyl ether of bisphenol-A epoxy hybrid resin
Daohong Zhang
Demin Jia
Sufang Chen
[J]. Journal of Thermal Analysis and Calorimetry, 2009, 98 : 819 - 824
[2] Kinetics of curing and thermal degradation of hyperbranched epoxy (HTDE)/diglycidyl ether of bisphenol-A epoxy hybrid resin
Zhang, Daohong
Jia, Demin
Chen, Sufang
[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (03) : 819 - 824
[3] Hyperbranched Polyphosphate Ester/Diglycidyl Ether of Bisphenol-A Epoxy Hybrid Resin: Preparation, Curing, and Thermal Degradation Kinetics
Zhang, Junheng
Chen, Sufang
Zhang, Daohong
Zhang, Aiqing
[J]. JOURNAL OF POLYMER MATERIALS, 2015, 32 (02): : 127 - 138
[4] Study on Curing Kinetics and Thermal Degradation Kinetics of Hyperbranched Poly(Trimellitic Anhydride Ethylene Glycol) Epoxy (HTME)/Diglycidyl Ether of Bisphenol-A Epoxy Hybrid Resin
Zhang, Daohong
Jia, Demin
[J]. POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2008, 47 (12) : 1220 - 1226
[5] Study on curing kinetics of a diglycidyl ether of bisphenol A epoxy resin/microencapsulated curing agent system
Wang Fang
Xiao Jun
Wang Jing-wen
Li Shu-qin
[J]. HIGH PERFORMANCE POLYMERS, 2012, 24 (08) : 730 - 737
[6] Study on Curing Kinetics and Curing Mechanism of Epoxy Resin Based on Diglycidyl Ether of Bisphenol A and Melamine Phosphate
[J]. Chang, F.-C. (Changfc@mail.nctu.edu.tw), 1600, John Wiley and Sons Inc. (92):
[7] Study on curing kinetics and curing mechanism of epoxy resin based on diglycidyl ether of bisphenol A and melamine phosphate
Chen, WY
Wang, YZ
Chang, FC
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (02) : 892 - 900
[8] Preparation and curing kinetics investigation of diglycidyl ether of bisphenol A/liquid crystalline epoxy resin blends
Yang, Xiao-Wang
Lu, Shao-Rong
Jiang, Yu-Mei
Zhang, Bo
Yu, Jin-Hong
[J]. IRANIAN POLYMER JOURNAL, 2008, 17 (04) : 251 - 264
[9] Study on the performance of diglycidyl ether of bisphenol-A/hyperbranched aromatic polyester epoxy resin (HTME) system and their toughness mechanism
Zhang, Daohong
Jia, Demin
[J]. POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2006, 45 (09) : 1005 - 1011
[10] Bisphenol-A epoxy resin reinforced and toughened by hyperbranched epoxy resin
Daohong Zhang
Demin Jia
Xianbo Huang
[J]. Frontiers of Chemical Engineering in China, 2007, 1 (4): : 349 - 354

← 1 2 3 4 5 →