High-pressure phase transition of bismuth

被引:8
|
作者
Ono, Shigeaki [1 ]
机构
[1] Japan Agcy Marine Earth Sci & Technol, Res & Dev Ctr Ocean Drilling Sci, 2-15 Natsushima Cho, Yokosuka, Kanagawa 2370061, Japan
关键词
Bismuth; high pressure; high temperature; x-ray diffraction; phase transition; IN-SITU OBSERVATION; CRYSTAL-STRUCTURE; STATE; BI;
D O I
10.1080/08957959.2018.1541456
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The high-pressure phase transition of bismuth, Bi, has been investigated using an in-situ X-ray powder diffraction measurement at pressures and temperatures up to 8.1GPa and 440K, respectively. The pressure-induced phase transition from Bi-III to Bi-V was observed. This transition occurred at 7.6GPa and at room temperature, where a negative temperature dependence for this transition was confirmed. The transition boundary was determined to be P(GPa) = 12.4 - 0.016 xT(K).
引用
收藏
页码:414 / 421
页数:8
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