Pd(OAc)2/PPh3-Catalyzed Desulfonylative Homocoupling of Arylsulfonyl Chlorides

被引：8
|
作者：
Zhao, Qiao [1 ]
Chen, Liangshun [1 ]
Lang, Hongyue [1 ]
Wu, Shengying [1 ]
Wang, Limin [1 ,2 ]
机构：
[1] E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 05期
基金：
中国国家自然科学基金;
关键词：
biaryls; arylsulfonyl chlorides; desulfonylative; palladium-catalyzed; ARENESULFONYL CHLORIDES; SULFONYL CHLORIDES; ARYLBORONIC ACIDS; GRIGNARD-REAGENTS; HIGHLY EFFICIENT; CROSS-COUPLINGS; PALLADIUM; ARYL; OLIGOMERS; OXYGEN;
D O I：
10.1002/cjoc.201400868
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Pd-catalyzed homodimerization with respect to arylsulfonyl chlorides as an efficient method for the synthesis of biaryls has been developed. This desulfonylative reaction which was performed at reflux in 1,4-dioxane for 4 h under air afforded the desired products in good to excellent yields.
引用
收藏
页码：535 / 538
页数：4
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