Lignin Functionalization Strategies and the Potential Applications of Its Derivatives-A Review

被引:28
|
作者
Suota, Maria Juliane [1 ]
Kochepka, Debora Merediane [1 ]
Moura, Marlon Gualberto Ganter [1 ]
Pirich, Cleverton Luiz [1 ]
Matos, Mailson [2 ]
Magalhaes, Washington Luiz Esteves [2 ,3 ]
Ramos, Luiz Pereira [1 ]
机构
[1] Fed Univ Parana UFPR, Dept Chem, BR-81531980 Curitiba, Parana, Brazil
[2] Fed Univ Parana UFPR, Grad Program Mat Sci & Engn, BR-81531980 Curitiba, Parana, Brazil
[3] Embrapa Florestas, BR-83411000 Colombo, PR, Brazil
关键词
Lignin functionalization; Derivatized lignin; Biobased products; Value-added materials; SOFTWOOD KRAFT LIGNIN; MANNICH REACTION; LIGNOCELLULOSIC BIOMASS; CHEMICAL-MODIFICATION; ENGINEERING PLASTICS; ORGANOSOLV LIGNIN; AMINATED LIGNIN; ALKALI LIGNIN; CU(II) IONS; METHYLATION;
D O I
10.15376/biores.16.3.Suota
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Lignin is one of the most important and widespread carbon sources on Earth. Significant amounts of lignin are delivered to the market by pulp mills and biorefineries, and there have been many efforts to develop routes for its valorization. Over the years, lignin has been used to produce biobased chemicals, materials, and advanced biofuels on the basis of its variable functionalities and physicochemical properties. Today, lignin's applications are still limited by its heterogeneity, variability, and low reactivity. Thus, modification technologies have been developed to allow lignin to be suitable for a wider range of attractive industrial applications. The most common modifications used for this purpose include amination, methylation, demethylation, phenolation, sulfomethylation, oxyalkylation, acylation or esterification, epoxidation, phosphorylation, nitration, and sulfonation. This article reviews the chemistry involved in these lignin modification technologies, discussing their effect on the finished product while presenting some market perspectives and future outlook to utilize lignin in sustainable biorefineries.
引用
收藏
页码:6471 / 6511
页数:41
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