Chemical vapor transport of intermetallic systems .3. Chemical transport of Mo/W-mixed crystals

被引：9

作者：

Neddermann, R ^{[1
]}

Gerighausen, S ^{[1
]}

Binnewies, M ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ANORGAN CHEM,D-30167 HANNOVER,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 01期

关键词：

chemical transport reactions; Mo/W-mixed crystals;

D O I：

10.1002/zaac.19966220105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mo/W-mixed crystals can be prepared by means of chemical vapor transport with HgBr2 (1 000 degrees C --> 900 degrees C). It is known [2] that the transport reaction of tungsten begins hours or even days after starting the experiment. This is the reason for the unusual composition of deposited crystals: EDX-analysis show them to have a Mo-rich nucleus and a W-rich shell.

引用

页码：21 / 23

页数：3

共 50 条

[1] Chemical Vapor Transport of Intermetallic Systems. 3. Chemical Transport of Mo/W-mixed Crystals
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