Shaping the Future of Fuel: Monolithic Metal-Organic Frameworks for High-Density Gas Storage

被引：192
|
作者：
Connolly, Bethany M. [2 ]
Madden, David [2 ]
Wheatley, Andrew [1 ]
Fairen-Jimenez, David [2 ]
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ Cambridge, Dept Chem Engn & Biotechnol, Adsorpt & Adv Mat Lab A2ML, Cambridge CB3 0AS, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 19期
基金：
英国工程与自然科学研究理事会; 欧洲研究理事会; “创新英国”项目;
关键词：
HYDROGEN STORAGE; METHANE STORAGE; NATURAL-GAS; ADSORPTION; SEPARATION; PRESSURE; DESIGN; TEMPERATURE; ADSORBENTS; STRATEGIES;
D O I：
10.1021/jacs.0c00270
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The environmental benefits of cleaner, gaseous fuels such as natural gas and hydrogen are widely reported. Yet, practical usage of these fuels is inhibited by current gas storage technology. Here, we discuss the wide-ranging potential of gas-fuels to revolutionize the energy sector and introduce the limitations of current storage technology that prevent this transition from taking place. The practical capabilities of adsorptive gas storage using porous, crystalline metal-organic frameworks (MOFs) are examined with regard to recent benchmark results and ultimate storage targets in this field. In particular, the industrial limitations of typically powdered MOFs are discussed while recent breakthroughs in MOF processing are highlighted. We offer our perspective on the future of practical, rather than purely academic, MOF developments in the increasingly critical field of environmental fuel storage.
引用
收藏
页码：8541 / 8549
页数：9
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