Copper(II) camphorates with tunable pore size in metal-organic frameworks

被引：13
|
作者：
Dybtsev, D. N. [1 ,2 ]
Yutkin, M. P. [1 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
copper(II) complexes; coordination polymers; frameworks; chiral structures; powder X-ray diffraction; COORDINATION POLYMERS; DESIGN; SEPARATION; CATALYSIS; POROSITY;
D O I：
10.1007/s11172-009-0313-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three new homochiral metal-organic coordination polymers [Cu(2)camph(2)dabco] center dot DMF center dot 2H(2)O, [Cu(2)camph(2)bipy] center dot 3DMF center dot 2H(2)O, and [Cu(2)camph(2)bpe] center dot 4DMF center dot 2H(2)O (H(2)camph is (+)-camphoric acid, bipy is 4,4'-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.
引用
收藏
页码：2246 / 2249
页数：4
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