Ethylene Oligomerization by Tridentate Cobalt Complexes Bearing Pendant Donor Modified α-Diimine Ligands

被引：10
|
作者：
Bahuleyan, Bijal Kottukkal [1 ]
Ahn, In Yong [1 ]
Appukuttan, Vinukrishnan [1 ]
Lee, So Hyun [1 ]
Ha, Chang-Sik [1 ]
Kim, Il [1 ]
Suh, Hongsuk [2 ,3 ]
机构：
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, WCU Ctr Synthet Polymer Bioconjugate Hybrid Mat, Pusan 609735, South Korea
[2] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea
[3] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea
来源：
MACROMOLECULAR RESEARCH | 2010年 / 18卷 / 07期
关键词：
catalysis; ethylene oligomerization; transition metal chemistry; CATALYSTS; POLYMERIZATION;
D O I：
10.1007/s13233-010-0710-y
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of tridentate cobalt complexes of the general formula [RN(CH2)(2)N]=An=[N(2,6-C(6)H(3)iPr)] (R=Me, Et, iPr; An=acenaphthenequinone) have been synthesized. All complexes were active towards ethylene oligomerization, showing activities exceeding 10(4) g-oligomer/mol-Co.h.bar in the presence of a methylaluminoxane co-catalyst. 1-Butene and trans-2-hexene were the major oligomer fractions obtained.
引用
收藏
页码：701 / 704
页数：4
相关论文
共 50 条
  • [1] Ethylene oligomerization by tridentate cobalt complexes bearing pendant donor modified α-diimine ligands
    Bijal Kottukkal Bahuleyan
    In Yong Ahn
    Vinukrishnan Appukuttan
    So Hyun Lee
    Chang-Sik Ha
    Il Kim
    Hongsuk Suh
    [J]. Macromolecular Research, 2010, 18 : 701 - 704
  • [2] Oligomerization of ethylene using new iron catalysts bearing pendant donor modified α-diimine ligands
    Small, Brooke L.
    Rios, Ray
    Fernandez, Eric R.
    Carney, Michael J.
    [J]. ORGANOMETALLICS, 2007, 26 (07) : 1744 - 1749
  • [3] Oligomerization of Ethylene Using New Tridentate Iron Catalysts Bearing α-Diimine Ligands with Pendant S and P Donors
    Small, Brooke L.
    Rios, Ray
    Fernandez, Eric R.
    Gerlach, Deidra L.
    Halfen, Jason A.
    Carney, Michael J.
    [J]. ORGANOMETALLICS, 2010, 29 (24) : 6723 - 6731
  • [4] Ethylene oligomerization promoted by chromium complexes bearing imine tridentate ligands
    Pinheiro, Adriana
    Bergamo, Adao
    Casagrande, Adriana
    Kirillov, Evgueni
    Carpentier, Jean-Francois
    Casagrande, Osvaldo
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [5] Cobalt-β-diimine complexes for ethylene oligomerization
    Caovilla, Marcela
    Thiele, Daniel
    de Souza, Roberto F.
    Gregorio, Jose R.
    Bernardo-Gusmao, Katia
    [J]. CATALYSIS COMMUNICATIONS, 2017, 101 : 85 - 88
  • [6] Ethylene oligomerization by cobalt(II) diimine complexes/EAO
    Qian, MX
    Wang, M
    Zhou, B
    He, R
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 209 (1-2) : 11 - 15
  • [7] Ethylene oligomerization by cobalt(II) diimine complexes/EAO
    Zhou, B
    Qian, MX
    Wang, M
    He, R
    [J]. ADVANCES ON ORGANOMETALLIC CATALYSTS AND OLEFIN POLYMERIZATION IN CHINA AND GERMANY, 2001, : 143 - 148
  • [8] Oligomerization of ethylene using tridentate nickel catalysts bearing ether-pyrazol ligands with pendant O- and S-donor groups
    Ulbrich, Ana H. D. P. S.
    Bergamo, Adao L.
    Casagrande, Osvaldo de L., Jr.
    [J]. CATALYSIS COMMUNICATIONS, 2011, 16 (01) : 245 - 249
  • [9] Synthesis, Characterization and Ethylene Oligomerization Studies of Nickel Complexes Bearing Novel Bis-α-diimine Ligands
    Netalkar, Sandeep P.
    Netalkar, Priya P.
    Sathisha, M. P.
    Budagumpi, Srinivasa
    Revankar, Vidyanand K.
    [J]. CATALYSIS LETTERS, 2014, 144 (01) : 181 - 191
  • [10] Synthesis, Characterization and Ethylene Oligomerization Studies of Nickel Complexes Bearing Novel Bis-α-diimine Ligands
    Sandeep P. Netalkar
    Priya P. Netalkar
    M. P. Sathisha
    Srinivasa Budagumpi
    Vidyanand K. Revankar
    [J]. Catalysis Letters, 2014, 144 : 181 - 191
12345