Kinetics of low-temperature oxidative chlorination of benzene in aqueous acetic acid

被引：3
|
作者：
Rudakova, NI [1 ]
Erykalov, YG [1 ]
机构：
[1] Ivanovo State Univ, Ivanovo 153377, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2005年 / 75卷 / 05期
关键词：
D O I：
10.1007/s11176-005-0312-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of chlorination of benzene with a mixture of sodium peroxide with hydrochloric acid in aqueous acetic acid at 298 K was studied. The chlorination rate is the highest when the AcOH concentration in the binary solvent is 49.4-40.6 mol % and the ratio of the initial cocentrations of water and sodium peroxide, 18.5-20.2. The linear dependences of log k(app) on the AcOH concentration and [H2O](0)/ [Na2O2](0) ratio were obtained.
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页码：748 / 750
页数：3
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