Reactions of laser-ablated niobium and tantalum atoms with NO.: Infrared spectra of the NMO, M(η1-NO)x (x = 2, 3), and (N2)(MO2) molecules in solid argon

被引：16

作者：

Zhou, MF ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22901 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1998年 / 102卷 / 49期

关键词：

D O I：

10.1021/jp983392t

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-ablated Nb and Ta atoms react with NO to give primarily the NNbO and NTaO insertion products, which are identified from isotopic substitution and density functional calculations of isotopic frequencies. Although the mononitrosyls are not observed, annealing gives dinitrosyls the trinitrosyls for both metals. Photolysis markedly increases (N-2)(NbO2) and (N-2)(TaO2), which are stable end products for these reactions.

引用

页码：10025 / 10031

页数：7

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