Recent Advances in Transition Metal-Promoted Trifluoromethylation Reactions

被引：14
|
作者：
Chen, Donghan [1 ]
Yang, Wen [1 ]
Yao, Yongqi [1 ]
Yang, Xin [1 ]
Deng, Yingying [1 ]
Yang, Dingqiao [1 ]
机构：
[1] South China Normal Univ, Sch Chem & Environm, Minist Educ, Key Lab Theoret Chem Environm, Guangzhou 510006, Guangdong, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 38卷 / 10期
基金：
中国国家自然科学基金;
关键词：
transition metal; trifluoromethylation; research progress; PALLADIUM-CATALYZED TRIFLUOROMETHYLATION; PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION; MEDIATED OXIDATIVE TRIFLUOROMETHYLATION; FORMING REDUCTIVE ELIMINATION; C-H TRIFLUOROMETHYLATION; FACILE SYNTHESIS; DECARBOXYLATIVE TRIFLUOROMETHYLATION; DENITRATIVE TRIFLUOROMETHYLATION; UNACTIVATED ALKENES; SILVER;
D O I：
10.6023/cjoc201803045
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recently, transition metal-promoted trifluoromethylation has been developed rapidly. Starting with the types of transition metal that promote the trifluoromethylation reactions, the research progress of trifluoromethylation promoted by silver, iron, palladium, nickel, rhodium and cobalt in recent years is reviewed. Moreover, the possible mechanisms of some parts of reactions are also discussed.
引用
收藏
页码：2571 / 2589
页数：19
相关论文
共 83 条
  • [1] Aryl-CF3 Bond-Forming Reductive Elimination from Palladium(IV)
    Ball, Nicholas D.
    Kampf, Jeff W.
    Sanford, Melanie S.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (09) : 2878 - +
  • [2] Boswell G.A., 1974, ORG REACT, V21, P1
  • [3] The Palladium-Catalyzed Trifluoromethylation of Vinyl Sulfonates
    Cho, Eun Jin
    Buchwald, Stephen L.
    [J]. ORGANIC LETTERS, 2011, 13 (24) : 6552 - 6555
  • [4] The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides
    Cho, Eun Jin
    Senecal, Todd D.
    Kinzel, Tom
    Zhang, Yong
    Watson, Donald A.
    Buchwald, Stephen L.
    [J]. SCIENCE, 2010, 328 (5986) : 1679 - 1681
  • [5] Carbon-carbon bond-forming reductive elimination from arylpalladium complexes containing functionalized alkyl groups. Influence of ligand steric and electronic properties on structure, stability, and reactivity
    Culkin, DA
    Hartwig, JF
    [J]. ORGANOMETALLICS, 2004, 23 (14) : 3398 - 3416
  • [6] Oxidative Trifluoromethylation of Unactivated Olefins: An Efficient and Practical Synthesis of α-Trifluoromethyl-Substituted Ketones
    Deb, Arghya
    Manna, Srimanta
    Modak, Atanu
    Patra, Tuhin
    Maity, Soham
    Maiti, Debabrata
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (37) : 9747 - 9750
  • [7] Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group
    Egami, Hiromichi
    Shimizu, Ryo
    Usui, Yoshihiko
    Sodeoka, Mikiko
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (66) : 7346 - 7348
  • [8] Iron-Catalyzed Decarboxylation of Trifluoroacetate and Its Application to the Synthesis of Trifluoromethyl Thioethers
    Exner, Benjamin
    Bayarmagnai, Bilguun
    Jia, Fan
    Goossen, Lukas J.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (48) : 17220 - 17223
  • [9] Catalysis for fluorination and trifluoromethylation
    Furuya, Takeru
    Kamlet, Adam S.
    Ritter, Tobias
    [J]. NATURE, 2011, 473 (7348) : 470 - 477
  • [10] Unexpected H2O-induced Ar-X activation with trifluoromethylpalladium(II) aryls
    Grushin, VV
    Marshall, WJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (14) : 4632 - 4641
123456789