Miscibility and specific interactions in poly(β-hydroxybutyrate-co-β-hydroxyvalerate) and poly(P-vinylphenol) blends

被引:10
|
作者
Xing, PX [1 ]
Dong, LS
Feng, ZL
Feng, HQ
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Phys Lab, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Wuhan Inst Phys, Wuhan 430071, Peoples R China
关键词
D O I
10.1016/S0014-3057(97)00198-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The blends of poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (P(HB-co-HV)/poly(p-vinylphenol)(PVPh) were investigated by differential scanning calorimetry (DSC), Fourier transform IR (FT-IR) spectroscopy and high-resolution solid-state C-13 NMR techniques. Single glass transition temperatures existing in the whole composition range indicates that these blends are miscible. The presence of hydrogen bonding between the hydroxyl of PVPh and carbonyl of P(HB-co-HV), shown by FT-IR spectra, is the origin of the miscibility. Furthermore, results obtained by high-resolution solid-state C-13 NMR give more information about the structure of the blends. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1207 / 1211
页数:5
相关论文
共 50 条
  • [1] Miscibility and specific interactions in polyacrylonitrile/poly(p-vinylphenol) blends
    Goh, SH
    Lee, SY
    Yeo, YT
    Zhou, X
    Tan, KL
    MACROMOLECULAR RAPID COMMUNICATIONS, 1999, 20 (03) : 148 - 151
  • [2] Miscibility and crystallization of poly(beta-hydroxybutyrate) and poly(p-vinylphenol) blends
    Xing, PX
    Dong, LS
    An, YX
    Feng, ZL
    Avella, M
    Martuscelli, E
    MACROMOLECULES, 1997, 30 (09) : 2726 - 2733
  • [3] Miscibility and interactions in poly(methylthiomethyl methacrylate)/poly(p-vinylphenol) blends
    Yi, JZ
    Goh, SH
    Wee, ATS
    MACROMOLECULES, 2001, 34 (21) : 7411 - 7415
  • [4] Compatibility and specific interactions in poly(beta-hydroxybutyrate) and poly(p-vinylphenol) blends
    Xing, PX
    Dong, LS
    Feng, HQ
    An, YX
    Zhuang, YG
    Feng, ZL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (11): : 1813 - 1815
  • [5] Miscibility and interactions in poly(N-acryloylthiomorpholine)/poly(p-vinylphenol) blends
    Yi, JZ
    Goh, SH
    Wee, ATS
    MACROMOLECULES, 2001, 34 (13) : 4662 - 4665
  • [7] Miscibility of poly(1-vinylimidazole)/poly(p-vinylphenol) blends
    Goh, SH
    Lee, SY
    Tan, LIK
    POLYMER BULLETIN, 1996, 37 (02) : 253 - 257
  • [8] Miscibility and Rheology Behaviors of Poly(3-hydroxybutyrate)/Poly(p-vinylphenol) Blends with Homogeneous Amorphous Compositions
    Ding, Guangzhu
    Cui, Kun
    Liu, Jieping
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (01) : 617 - 623
  • [9] Miscibility and interactions in blends and complexes of poly[2-(dimethylamino)ethyl methacrylate] with poly(p-vinylphenol)
    Huang, XD
    Goh, SH
    Lee, SY
    Zhao, ZD
    Wong, MW
    Huan, CHA
    MACROMOLECULES, 1999, 32 (13) : 4327 - 4331
  • [10] Miscibility and interactions in blends and complexes of poly(N-acryloyl-N′-methylpiperazine) with poly(p-vinylphenol)
    Liu, Y
    Goh, SH
    Lee, SY
    Huan, CHA
    MACROMOLECULES, 1999, 32 (06) : 1967 - 1971