Conversion of Waste Biomass into Activated Carbon and Evaluation of Environmental Consequences Using Life Cycle Assessment

被引:17
|
作者
Amin, Muhammad [1 ]
Shah, Hamad Hussain [2 ]
Iqbal, Amjad [3 ,4 ]
Farooqi, Zia Ur Rahman [5 ]
Krawczuk, Marek [6 ]
Zia, Adeel [7 ]
机构
[1] Seoul Natl Univ, Dept Energy Syst Engn, Seoul 08826, South Korea
[2] Univ Sannio, Dept Engn, Piazza Roma 21, I-82100 Benevento, Italy
[3] Silesian Tech Univ, Fac Mat Engn, Dept Adv Mat & Technol, PL-44100 Gliwice, Poland
[4] Univ Coimbra, CEMMPRE Ctr Mech Engn Mat & Proc, Dept Mech Engn, Rua Luis Reis Santos, P-3030788 Coimbra, Portugal
[5] Univ Aberdeen, Sch Biol Sci, Inst Biol & Environm Sci, 23 St Machar Dr, Aberdeen AB24 3UU, Scotland
[6] Gdansk Univ Technol, Fac Mech Engn & Ship Technol, Inst Mech & Machine Design, Narutowicza 11-12, PL-80233 Gdansk, Poland
[7] Southern Illinois Univ, Sch Chem & Biomol Sci, Carbondale, IL 62901 USA
来源
APPLIED SCIENCES-BASEL | 2022年 / 12卷 / 11期
关键词
activated carbon; life cycle assessment; H3PO4; chemical activation; CHEMICAL ACTIVATION; LANTANA-CAMARA; REMOVAL; IMPACT;
D O I
10.3390/app12115741
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this article, activated carbon was produced from Lantana camara and olive trees by H3PO4 chemical activation. The prepared activated carbons were analyzed by characterizations such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, thermogravimetric analysis, and Fourier transform infrared spectroscopy. H3PO4 is used as an activator agent to create an abundant pore structure. According to EDX analysis, the crystalline structure destroys and increases the carbon content of the olive tree and Lantana camara by 77.51 and 76.16%, respectively. SEM images reveal a porous structure formed as a result of H3PO4 activation. The Brunauer-Emmett-Teller (BET) surface area of the olive tree and Lantana camara activated carbon was 611.21 m(2)/g and 167.47 m(2)/g, respectively. The TGA analysis of both activated carbons shows their thermal degradation starts at 230 degrees C but fully degrades at temperatures above 450 degrees C. To quantify the potential environmental implications related to the production process of the activated carbon (AC) from olive trees, the life cycle assessment (LCA) environmental methodology was employed. For most of the tested indicators, chemical activation using H3PO4 showed the greatest ecological impacts: the ozone layer depletion potential (42.27%), the acidification potential (55.31%), human toxicity (57.00%), freshwater aquatic ecotoxicity (85.01%), terrestrial ecotoxicity (86.17%), and eutrophication (92.20%). The global warming potential (5.210 kg CO2 eq), which was evenly weighted between the phases, was shown to be one of the most significant impacts. The total energy demand of the olive tree's AC producing process was 70.521 MJ per Kg.
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页数:12
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