A cobalt-based coordination polymer with a tripodal carboxylate ligand: synthese, structure and properties

被引：0

作者：

Tang, Long ^{[1
]}

Nan, JiaoWei ^{[1
]}

Zheng, YuFei ^{[1
]}

Wang, JiJiang ^{[1
]}

Hou, XiangYang ^{[1
]}

Wang, Xiao ^{[1
]}

机构：

[1] Yanan Univ, Key Lab New Energy & New Funct Mat, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2021年 / 76卷 / 08期

基金：

中国国家自然科学基金;

关键词：

cobalt(II) complex; coordination polymer; cyclovoltammetry; fluorescence; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENCE; EFFICIENT; MODULATION; ADSORPTION; SERIES; MOFS;

D O I：

10.1515/znb-2021-0074

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new cobalt-based coordination polymer (CP), [Co(Htatb)(1,4-bib)]center dot DMF (1), has been hydrothermally synthesized from CoCl2 center dot 6H(2)O, 4,4',4 ''-s-triazine-2,4,6-tribenzoic acid (H(3)tatb), and 1,4-bis(1-imidazoly)benzene (1,4-bib). The product has been characterized by IR spectroscopy, elemental and thermogravimetric analysis, and singlecrystal X-ray diffraction. In compound 1, the Htatb ligand links three Co-II ions resulting in a double-strand chain structure, further bridged through the 1,4-bib ligands to generate a 2D structure with channels. The fluorescence and cyclovoltammetry characteristics of compound 1 have also been investigated.

引用

页码：447 / 452

页数：6

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