Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

被引：13
|
作者：
Ahammed, Sabir [1 ]
Saha, Amit [1 ]
Ranu, Brindaban C. [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, India
来源：
RSC ADVANCES | 2012年 / 2卷 / 15期
关键词：
DERIVATIVES; COMPLEXES; EFFICIENT; SOLVENTS; ARYL;
D O I：
10.1039/c2ra20856c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A convenient and efficient procedure for the synthesis of S-allyl/cinnamyl dithiocarbamates has been developed by a one-pot reaction of allyl/cinnamyl acetate, carbon disulfide and amine in presence of Ru(acac)(3) in water. A variety of functionalized dithiocarbamates have been obtained by this procedure in high yields. The reaction proceeds via a catalytic Ru(II) species, generated in situ during the reaction.
引用
收藏
页码：6329 / 6335
页数：7
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