A photoluminescent 3D silver(I) coordination polymer with mixed ligands anthracene-9,10-dicarboxylate and hexamethylenetetramine, showing binodal 4-connected (43.63)2(42.62.82)3 topology

被引：37

作者：

Liu, Chun-Sen ^{[1
,2
]}

Chang, Ze ^{[1
]}

Wang, Jun-Jie ^{[1
]}

Yan, Li-Fen ^{[1
]}

Bu, Xian-He ^{[1
]}

Batten, Stuart R. ^{[3
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China

[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 08期

基金：

中国国家自然科学基金;

关键词：

silver(I) complex; anthracene-based ligand; crystal structure; topology; luminescence;

D O I：

10.1016/j.inoche.2008.04.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of AgClO4 with anthracene-9,10-dicarboxylic acid (H2L) and hexamethylenetetramine(hmt) in the presence of 2,6-dimethylpyridine afforded a photoluminescent three-dimensional (3D) Ag-1 coordination polymer {[Ag-8(L)(3)(mu 4-hmt)2(H2O)(6)](ClO4)(2)}(infinity) (L = anthracene-9,10-dicarboxylate) exhibiting binodal 4-connected (4(3).6(3))(2)(4(2)-6(2).8(2))(3) topological network. The relevant result reveals that the anthracene skeleton of L ligand bearing a large pi-conjugated ring system plays an important role in the formation of the final structure. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：889 / 892

页数：4

共 20 条

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