Density Functional Theory-Based Molecular Modeling: Verification of Decisive Roles of Van der Waals Aggregation of Triiodide Ions for Effective Electron Transfer in Wet-Type N3-Dye-Sensitized Solar Cells

Density functional theory-based molecular modeling (DFT/MM) validates that KI and I-2 undergo exothermic van der Waals (vdW) aggregation in acetonitrile (AN) or in the presence of 4-tert-butylpyridine (TBP), forming potassium triiodide (KI3) and, further mutual vdW aggregation leads to the formation of (KI3)(2) and AN, (KI3)(2) and (AN)(2) and (KI3)(2) and TBP in the AN-based Dye sensitized solar cells (DSSC) electrolytes. All KI3 aggregates have a very low energy gap, 0.17 eV, 0.14 eV and 0.05 eV of lowest unoccupied molecular orbital (LUMO) + 1 and LUMO, respectively, verifying efficient electron diffusion in mu m-thick DSSC electrolytes. Hydrogen-bonding aggregation of anatase TiO2 model, Ti9O18H and OH, with N3 (proton) dye is also validated by DFT/MM, and the energy structure verifies unidirectional electron flow from highest occupied molecular orbital (HOMO) on thiocyanide (SCN) groups of N3 dye to LUMO on the TiO2 model at the aggregates. Further, DFT/MM for the aggregation of K+I3- with N3 verifies the most exothermic formation of the aggregate of N3 (proton) and K+I3-. The UV-Vis spectra of N3 (proton) and K+I3- is consistent with reported incident photocurrent efficiency (IPCE) action spectra (lambda = 450-800 nm) of N3-sensitized DSSC, verifying that the N3 dye of N3 (proton) and K+I3- becomes an effective sensitizer in the anode / TiO2 / N3 (proton) / KI/I-2 / acetonitrile (AN) / cathode structured DSSC. The energy structure of LUMO and LUMO + 1 of the aggregates, Ti9O18H and OH and N3 (proton), N3 and K+I3-, (KI3)(2) and AN and (KI3)(2) and TBP verifies high IPCE photocurrent and effective electron diffusion via KI3-aggregates in the DSSC of Ti9O18H and OH and N3 (proton) and K+I3-.