Photocatalytic degradation of acridine dyes using anatase and rutile TiO2

被引:25
|
作者
Zubieta, C. E. [1 ]
Messina, P. V. [2 ,3 ]
Schulz, P. C. [2 ,3 ]
机构
[1] Univ Nacl Sur, IFISUR, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[3] Consejo Nacl Invest Cient & Tecn, INQUISUR, Bahia Blanca, Buenos Aires, Argentina
关键词
Titania; Microemulsion; Photodegradation; Pollution; Acridine dyes; Adsorption;
D O I
10.1016/j.jenvman.2012.02.014
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The adsorption and photodegradation of acridine orange (AO) and acriflavine (AF) dyes on two mesoporous titania crystalline phases, anatase and rutile, were experimentally studied. Anatase and rutile were characterized by nitrogen adsorption, electron scanning and transmission microscopy, and X-ray diffraction. The adsorption capacity of rutile was higher than that of anatase, while the reverse is observed for photodegradation of both dyes. The adsorption of AF on both adsorbents was higher than that of AO, which was related with the smaller size of AF molecules compared with those of AO, therefore the access of AF to the adsorption sites is favored. (c) 2012 Published by Elsevier Ltd.
引用
收藏
页码:1 / 6
页数:6
相关论文
共 50 条
  • [1] Photocatalytic degradation of dyes and organic contaminants in water using nanocrystalline anatase and rutile TiO2
    Tayade, Rajesh J.
    Surolia, Praveen K.
    Kulkarni, Ramchandra G.
    Jasra, Raksh V.
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2007, 8 (06) : 455 - 462
  • [2] Enhanced photocatalytic degradation of rutile/anatase TiO2 heterojunction nanoflowers
    Xu, Haifeng
    Li, Guang
    Zhu, Guang
    Zhu, Kerong
    Jin, Shaowei
    CATALYSIS COMMUNICATIONS, 2015, 62 : 52 - 56
  • [3] Photocatalytic Degradation of Rhodamine B on Anatase, Rutile, and Brookite TiO2
    Zhang Jing
    Yan Song
    Fu Lu
    Wang Fei
    Yuan Mengqiong
    Luo Genxiang
    Xu Qian
    Wang Xiang
    Li Can
    CHINESE JOURNAL OF CATALYSIS, 2011, 32 (06) : 983 - 991
  • [4] PHOTOCATALYTIC DEGRADATION OF PHENOL BY TIO2 AQUEOUS DISPERSIONS - RUTILE AND ANATASE ACTIVITY
    SCLAFANI, A
    PALMISANO, L
    DAVI, E
    NEW JOURNAL OF CHEMISTRY, 1990, 14 (04) : 265 - 268
  • [5] PHOTOCATALYTIC DEGRADATION OF CHLOROFORM WITH RUTILE-ANATASE MIXED TIO2 POWDER
    MURABAYASHI, M
    ITOH, K
    FURUSHIMA, H
    CHEN, D
    DENKI KAGAKU, 1991, 59 (06): : 524 - 525
  • [6] Photocatalytic nanocomposite anatase–rutile TiO2 coating
    Fatemehsadat Moosavi
    Alex Lemarchand
    Cyrille Bazin
    Maria Konstantakopoulou
    Mathieu Frégnaux
    Christophe Colbeau-Justin
    Touraj Tavakoli Gheinani
    Andrei Kanaev
    Mehrdad Nikravech
    Applied Physics A, 2022, 128
  • [7] Photocatalytic degradation of various dyes by combustion synthesized nano anatase TiO2
    Sivalingam, G
    Nagaveni, K
    Hegde, MS
    Madras, G
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 45 (01) : 23 - 38
  • [8] Evaluating Intrinsic Photocatalytic Activities of Anatase and Rutile TiO2 for Organic Degradation in Water
    Sun, Qiong
    Xu, Yiming
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (44): : 18911 - 18918
  • [9] Photocatalytic nanocomposite anatase-rutile TiO2 coating
    Moosavi, Fatemehsadat
    Lemarchand, Alex
    Bazin, Cyrille
    Konstantakopoulou, Maria
    Fregnaux, Mathieu
    Colbeau-Justin, Christophe
    Gheinani, Touraj Tavakoli
    Kanaev, Andrei
    Nikravech, Mehrdad
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2022, 128 (11):
  • [10] A patterned TiO2(anatase)/TiO2(rutile) bilayer-type photocatalyst:: Effect of the anatase/rutile junction on the photocatalytic activity
    Kawahara, T
    Konishi, Y
    Tada, H
    Tohge, N
    Nishii, J
    Ito, S
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (15) : 2811 - +