From vinyl sulfides, sulfoxides and sulfones to vinyl zirconocene derivatives

被引：52

作者：

Farhat, S ^{[1
]}

Zouev, I ^{[1
]}

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

TETRAHEDRON | 2004年 / 60卷 / 06期

基金：

以色列科学基金会;

关键词：

D O I：

10.1016/j.tet.2003.08.074

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An easy and straightforward new method for the preparation of Sp(2) zirconocene derivatives from a wide range of heterosubstituted alkenes such as vinyl sulfides, sulfoxides and sulfones is described. In all cases, a complete isomerization of the stereochemistry is observed and only the E-isomer is obtained. The reactivity of the resulting vinylic organometallic can be increased by a transmetalation reaction into organocopper, organozinc or organopalladium species and, therefore, several carbon-carbon formation were easily realized. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1329 / 1337

页数：9

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