Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration

被引：43
|
作者：
Callingham, Michael [1 ,2 ]
Partridge, Benjamin M. [1 ,3 ]
Lewis, William [1 ]
Lam, Hon Wai [1 ,2 ]
机构：
[1] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England
[2] Univ Nottingham, GSK Carbon Neutral Labs Sustainable Chem, Jubilee Campus,Triumph Rd, Nottingham NG7 2TU, England
[3] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 51期
基金：
欧洲研究理事会; 英国工程与自然科学研究理事会;
关键词：
allylation; asymmetric catalysis; imines; isomerization; rhodium; ALPHA; BETA-UNSATURATED DELTA-LACTONES; C-H FUNCTIONALIZATION; CHIRAL DIENE LIGANDS; CYCLIC IMINES; ASYMMETRIC CATALYSIS; CARBONYL-COMPOUNDS; NUCLEOPHILIC ALLYLATION; ALLENYL ALDEHYDES; PALLADIUM; KETIMINES;
D O I：
10.1002/anie.201709334
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
引用
收藏
页码：16352 / 16356
页数：5
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