A High-Rate Lithium Manganese Oxide-Hydrogen Battery

被引：38

作者：

Zhu, Zhengxin ^{[5
]}

Wang, Mingming ^{[6
]}

Meng, Yahan ^{[5
]}

Lin, Zihan ^{[5
]}

Cui, Yi ^{[1
,2
]}

Chen, Wei ^{[3
,4
]}

机构：

[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA

[2] SLAC Natl Accelerator Lab, Stanford Inst Mat & Energy Sci, Menlo Pk, CA 94025 USA

[3] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Appl Chem, Hefei 230026, Anhui, Peoples R China

[4] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Div Nanomat & Energy Convers, Hefei 230026, Anhui, Peoples R China

[5] Univ Sci & Technol China, Dept Appl Chem, Hefei 230026, Anhui, Peoples R China

[6] Univ Sci & Technol China, Sch Chem & Mat Sci, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

NANO LETTERS | 2020年 / 20卷 / 05期

关键词：

Hydrogen battery; lithium manganese oxide; hydrogen gas anode; grid-scale energy storage; REDOX-FLOW BATTERY; ENERGY-STORAGE; LIMN2O4; CHALLENGES;

D O I：

10.1021/acs.nanolett.0c00044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rechargeable hydrogen gas batteries show promises for the integration of renewable yet intermittent solar and wind electricity into the grid energy storage. Here, we describe a rechargeable, high-rate, and long-life hydrogen gas battery that exploits a nanostructured lithium manganese oxide cathode and a hydrogen gas anode in an aqueous electrolyte. The proposed lithium manganese oxide-hydrogen battery shows a discharge potential of similar to 1.3 V, a remarkable rate of 50 C with Coulombic efficiency of similar to 99.8%, and a robust cycle life. A systematic electrochemical study demonstrates the significance of the electrocatalytic hydrogen gas anode and reveals the charge storage mechanism of the lithium manganese oxide-hydrogen battery. This work provides opportunities for the development of new rechargeable hydrogen batteries for the future grid-scale energy storage.

引用

页码：3278 / 3283

页数：6

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