Kinetic of Adsorption Process of Sulfonated Carbon-derived from Eichhornia crassipes in the Adsorption of Methylene Blue Dye from Aqueous Solution

被引:7
|
作者
Nurhadi, Mukhamad [1 ]
Widiyowati, Iis Intan [1 ]
Wirhanuddin, W. [1 ]
Chandren, Sheela [2 ,3 ]
机构
[1] Univ Mulawarman, Dept Chem Educ, Kampus Gunung Kelua, Samarinda 75123, East Kalimantan, Indonesia
[2] Univ Teknol Malaysia, Fac Sci, Dept Chem, Johor Baharu 81310, Johor, Malaysia
[3] Univ Teknol Malaysia, Ibnu Sina Inst Sci & Ind Res, Ctr Sustainable Nanomat, Johor Baharu 81310, Johor, Malaysia
关键词
Eichhornia crassipes (water hyacinth); methylene blue; adsorption; sulfonation; carbon; TEXTILE DYES; BASIC-DYES; REMOVAL; BIOSORPTION; OXIDATION; EFFLUENTS; CATALYSTS; COAL;
D O I
10.9767/bcrec.14.1.2548.17-27
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The evaluation of kinetic adsorption process of sulfonated carbon-derived from Eichhornia crassipes in the adsorption of methylene blue dye from aqueous solution has been carried out. The sulfonated carbon- derived from E. crassipes (EGS-600) was prepared by carbonation of E. crassipes powder at 600 degrees C for 1 h, followed by sulfonation with concentrated sulfuric acid for 3 h. The physical properties of the adsorbents were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and nitrogen adsorption-desorption studies. Adsorption study using methylene blue dye was carried out by varying the contact time and initial dye concentration for investigated kinetics adsorption models. The effect of varying temperature was used to determine the thermodynamic parameter value of.G,.H, and.S. The results showed that the equilibrium adsorption capacity was 98% when EGS-600 is used as an adsorbent. The methylene blue dye adsorption onto adsorbent takes place spontaneity and follows a pseudo-second-order adsorption kinetic model. Copyright (c) 2019 BCREC Group. All rights reserved
引用
收藏
页码:17 / 27
页数:11
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