Experimental Study on Cyclohexane by Catalytic Oxidation Using H2O2/ferrous Sulfate

被引：0
|
作者：
Zhang, Jiaojing
Bai, Bing
Song, Hua
机构：
来源：
FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3 | 2011年 / 233-235卷
关键词：
ferrous sulfate; cyclohexane; catalytic oxidation; hydrogen peroxide; HYDROGEN-PEROXIDE;
D O I：
10.4028/www.scientific.net/AMR.233-235.1288
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol using hydrogen peroxide over ferrous sulfate catalyst at atmospheric condition was studied. Effect of the solvent volume, catalyst amount, hydrogen peroxide volume, reaction temperature, reaction time on reaction was investigated. Results showed that using 10 mL of acetone, 0.02 g of a ferrous sulfate and 0.5 mL of hydrogen peroxide at thereaction temperature of 80 degrees C for 8 h, the conversion of cyclohexane was 35.35%, the total selectivity of cyclohexanone and cyclohexanol was 94.06%.
引用
收藏
页码：1288 / 1291
页数：4
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