Bis[2-(hydroxymethyl)pyridine-κ2N,O]-dinitratocopper(II)

被引:8
|
作者
He, F [1 ]
Liu, D [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Sch Pharmaceut Sci, Guangzhou 510275, Peoples R China
关键词
D O I
10.1107/S1600536805018696
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, [Cu(NO3)2(C6H7NO)(2)], the copper(II) ion resides at an inversion centre and it has a 4 + 2 elongated ocatahedral coordination environment. The equatorial positions are occupied by two OH groups and two N atoms from a pair of neutral 2(hydroxymethyl) pyridine ligands, while the two axial positions are weakly ligated by two nitrate O atoms. Adjacent mononuclear copper(II) complexes are further joined together by O - H center dot center dot center dot O hydrogen bonds to form a linear chain along the a axis.
引用
收藏
页码:M1350 / M1351
页数:2
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