Regioisomeric donor-acceptor-donor triads based on benzodithiophene and BODIPY with distinct optical properties and mobilities

被引:14
|
作者
Sengupta, Sanchita [1 ]
Pandey, Upendra K. [1 ]
Athresh, Eashwer Umesh [1 ]
机构
[1] Indian Inst Sci, Interdisciplinary Ctr Energy Res ICER, CV Raman Rd, Bangalore 560012, Karnataka, India
关键词
ORGANIC SOLAR-CELLS; SMALL MOLECULES; PHOTOVOLTAIC PROPERTIES; CONJUGATED POLYMERS; CHARGE-TRANSPORT; DYES; DERIVATIVES; ABSORPTION; COPOLYMERS; ELECTRON;
D O I
10.1039/c6ra16791h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two regioisomeric triads D-A1-D and D-A2-D composed of benzodithiophene donors and BODIPY acceptors were synthesized and exhibited spectral coverage up to 700 nm due to efficient intramolecular charge transfer. Structural differences and planarity of these triads lead to distinct photoinduced electron transfer characteristics and charge carrier mobilities of up to similar to 10(-4) cm(2) V-1 s(-1).
引用
收藏
页码:73645 / 73649
页数:5
相关论文
共 50 条
  • [1] Benzothiadiazole-Dithienopyrrole Donor-Acceptor-Donor and Acceptor-Donor-Acceptor Triads: Synthesis and Optical, Electrochemical, and Charge-Transport Properties
    Polander, Lauren E.
    Pandey, Laxman
    Barlow, Stephen
    Tiwari, Prakash
    Risko, Chad
    Kippelen, Bernard
    Bredas, Jean-Luc
    Marder, Seth R.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (46): : 23149 - 23163
  • [2] Synthesis and properties of donor-acceptor-donor triads containing tetrathiafulvalene and naphthalene diimide units
    Guo, XF
    Zhang, DQ
    Xu, W
    Zhu, DB
    SYNTHETIC METALS, 2003, 137 (1-3) : 981 - 982
  • [3] Strategical Designing of Donor-Acceptor-Donor Based Organic Molecules for Tuning Their Linear Optical Properties
    Sen, Raja
    Singh, Samarendra P.
    Johari, Priya
    JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 122 (02): : 492 - 504
  • [4] Scanning tunneling microscopy and spectroscopy of donor-acceptor-donor triads at the liquid/solid interface
    Uji-i, H
    Miura, A
    Schenning, A
    Meijer, EW
    Chen, ZJ
    Würthner, F
    De Schryver, FC
    Van der Auweraer, M
    De Feyter, S
    CHEMPHYSCHEM, 2005, 6 (11) : 2389 - 2395
  • [5] Donor-Acceptor-Donor "Hot Exciton" Triads for High Reverse Intersystem Crossing in OLEDs
    Zhu, Yanan
    Vela, Sergi
    Meng, Hong
    Corminboeuf, Clemence
    Fumanal, Maria
    ADVANCED OPTICAL MATERIALS, 2022, 10 (16)
  • [6] Effects of Substituents on the Blue Luminescence of Disilane-Linked Donor-Acceptor-Donor Triads
    Usuki, Tsukasa
    Omoto, Kenichiro
    Shimada, Masaki
    Yamanoi, Yoshinori
    Kasai, Hidetaka
    Nishibori, Eiji
    Nishihara, Hiroshi
    MOLECULES, 2019, 24 (03)
  • [7] Physical, optical, electronic properties and mobility measurements of a new donor-acceptor-donor oligomer
    Kerner, Ross
    Li, Yilin
    Scudiero, Louis
    SYNTHETIC METALS, 2012, 162 (13-14) : 1198 - 1203
  • [8] Donor-Acceptor-Donor Triads with Flexible Spacers: Deciphering Complex Photophysics for Targeted Materials Design
    Feng, Siyang
    Wang, Liangxuan
    Milian-Medina, Begona
    Meixner, Alfred J.
    Kwon, Min Sang
    Park, Soo Young
    Wannemacher, Reinhold
    Gierschner, Johannes
    ADVANCED MATERIALS, 2023, 35 (44)
  • [9] Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor-acceptor-donor triads
    Avinash, M. B.
    Sandeepa, K. V.
    Govindaraju, T.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2013, 9 : 1565 - 1571
  • [10] An Electron-Accepting aza-BODIPY-Based Donor-Acceptor-Donor Architecture for Bright NIR Emission
    Kage, Yuto
    Kang, Seongsoo
    Mori, Shigeki
    Mamada, Masashi
    Adachi, Chihaya
    Kim, Dongho
    Furuta, Hiroyuki
    Shimizu, Soji
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (16) : 5259 - 5267