Thermal properties of modified banana trunk fibers

被引:11
|
作者
Sathasivam, Kathiresan [1 ]
Haris, Mas Rosemal Hakim Mas [2 ]
机构
[1] AIMST Univ, Fac Sci Appl, Dept Mat Sci, Bedong 08100, Kedah Darul Ama, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia
关键词
Apparent activation energy; Degradation models; Thermal decomposition; Modified fiber; Polymer composite; ICTAC KINETICS PROJECT; NATURAL FIBERS; DECOMPOSITION KINETICS; MECHANICAL-PROPERTIES; COMPUTATIONAL ASPECTS; POLYMER COMPOSITES; CELLULOSE; DEGRADATION; IMPROVEMENT; ACID;
D O I
10.1007/s10973-011-1793-1
中图分类号
O414.1 [热力学];
学科分类号
摘要
Thermal decomposition of an agrowaste, namely banana trunk fibers (BTF) were investigated by thermogravimetry (TG) and derivative thermogravimetry (DTG) up to 900 degrees C at different heating rates (from 5 to 100 degrees C/min). The BTF was subjected to modification by means of various known chemical methods (mercerization, acetylation, peroxide treatment, esterification, and sulfuric acid treatment). Various degradation models, such as the Kissinger, Friedman, and Flynn-Wall-Ozawa were used to determine the apparent activation energy. The obtained apparent activation energy values (149-210 kJ/mol) allow in developing a simplified approach to understand the thermal decomposition behavior of natural fibers as a function of polymer composite processing.
引用
收藏
页码:9 / 17
页数:9
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