Visible-light-induced sulfonylation/cyclization of vinyl azides: one-pot construction of 6-(sulfonylmethyl)phenanthridines

被引：56
|
作者：
Mao, Liu-Liang [1 ]
Zheng, Da-Gui [1 ]
Zhu, Xian-Hong [1 ]
Zhou, An-Xi [1 ]
Yang, Shang-Dong [2 ]
机构：
[1] Shangrao Normal Univ, Higher Inst Jiangxi Prov, Key Lab Appl Organ Chem, Shangrao 334001, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 02期
关键词：
TRANSITION-METAL-FREE; IMINYL-RADICAL FORMATION; ARYLSULFONYL CHLORIDES; PHOTOREDOX CATALYSIS; PHENANTHRIDINE DERIVATIVES; OXIDATIVE CYCLIZATION; FLUOROALKYLATION; 2-ISOCYANOBIPHENYLS; ISOCYANIDES; ARYLATION;
D O I：
10.1039/c7qo00790f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Visible-light-induced sulfonylation/cyclization of vinyl azides has been developed for the synthesis of 6-(sulfonylmethyl)-phenanthridines. This facile and efficient approach used simple and readily available sulfonyl chlorides as the sulfonylation reagent for the construction of C-S bonds and triggered the formation of the C-N bond with mild conditions, broad substrate scope, and high functional group tolerance.
引用
收藏
页码：232 / 236
页数：5
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