Crystal and molecular structure of a novel mixed ligand complex of tin(IV), [(Et(2)NCS(2))(2)Sn(O-C(CH3)=C(S)-C(O)-CH3)]

被引：9

作者：

Sharma, S ^{[1
]}

Bohra, R ^{[1
]}

Mehrotra, RC ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

POLYHEDRON | 1996年 / 15卷 / 09期

关键词：

D O I：

10.1016/0277-5387(95)00391-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recrystallization of [BrSn(S(2)CNEt(2))(2)(OC(CH3)CHCOCH3)] 1, formed from the reaction of Br2Sn(S(2)CNEt(2))(2) with Na(CH3COCHCOCH3) in 1:1 molar ratio yields [(Et(2)NCS(2))(2)Sn(O-C(CH3)=C(S)-C(O)-CH3)] 2, a unique derivative, which was characterized by X-ray crystallography. The geometry around tin(IV) is distorted octahedral, with the average Sn-S distance [2.548(4)Angstrom] of the chelated dithiocarbamate being longer than the Sn-S distance [2.388(5)Angstrom] of the five-membered chelating > Sn(O-C(CH3)=C(S)-C(O)-CH3) ligand moiety.

引用

页码：1525 / 1529

页数：5

共 50 条

[1] Crystal and molecular structure of a novel mixed ligand complex of tin(IV), [(Et2NCS2)2Sn(O-C(CH3)=C(S)-C(O)$M IN@CH3)$ RB@
Sharma, S.
Bohra, R.
Mehrotra, R. C.
Polyhedron, 15 (09):
[2] CRYSTAL AND MOLECULAR-STRUCTURES OF THE ACETYLACETONATE DERIVATIVES [SE(CH3C(O)CC(O)CH3)]2 AND [PHSE]2[CH3C(O)CC(O)CH3]
ADRIEN, RJ
GABLE, RW
HOSKINS, BF
DAKTERNIEKS, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 359 (01) : 33 - 39
[3] Thermal reaction of (CH3)(2)C=C(CH3)(2) in the presence of di-tert-butyl peroxide; Reactions of the radicals center dot CH3,(CH3)(3)C center dot C(CH3)(2) and (CH3)(2)C=C(CH3)center dot CH2
Kortvelyesi, T
Seres, L
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1996, 93 (02) : 253 - 273
[4] Intramolecular Rearrangements of >Si(O–C·=O)(CH2–CH3) and >Si(CH2–CH·–CH3)(CH2–CH3) Radicals
V. A. Radtsig
Kinetics and Catalysis, 2002, 43 : 484 - 494
[5] CRYSTAL AND MOLECULAR-STRUCTURE OF "[CH3C(S)CHC(S)CH3][CH3S(O)(CH2)2]NI
DUDIS, DS
FACKLER, JP
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 249 (01) : 289 - 292
[6] Crystal structure of 2,3-bis[O,O′-dimethylphenyl)iminobutane, [C6H3(CH3)2]2C2N2(CH3)2
Kuhn, N
Steimann, M
Walker, I
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2001, 216 (02): : 319 - 319
[7] REACTIVITY OF ISOPROPENYLACETYLENE, H-C=C-C(CH3)=CH2, IN THE PRESENCE OF THE COMPLEX [NI(NCS) (C=C-C(CH3)CH2)(PPH3)2]
FURLANI, A
RUSSO, MV
APPLIED ORGANOMETALLIC CHEMISTRY, 1990, 4 (04) : 319 - 327
[8] SYNTHESES OF CARBENE AND ALKENYL DERIVATIVES OF PALLADIUM - SOLID-STATE STRUCTURES OF ((ME(2)NCS(2))PD(PET(3))[ETA(1)-C(N(CH3)C(CH3)(3))CH3])BPH(4) AND ((ME(2)NCS(2))PD(PET(3))[ETA(1)-C(NHC(CH3)(3))CH3])PF6-CENTER-DOT-ET(2)O
REGER, DL
COLLINS, JE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 491 (1-2) : 159 - 167
[9] CRYSTAL AND MOLECULAR STRUCTURE OF [AL(CH3)3]2.C4H8O2
ATWOOD, JL
STUCKY, GD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) : 5362 - &
[10] A TETRANUCLEAR BETA-DIKETONATO COMPLEX OF ORGANOTIN(IV) - SYNTHESIS AND CRYSTAL-STRUCTURE OF (BENZOYLTRIFLUOROACETONATO)-(TRIFLUOROACETATO)TETRAMETHYLDISTANNOXANE DIMER [(C6H5C(O)CHCO(CF3)SN(CH3)2)O(SN(CH3)2O2CCF3)]2
AGARWAL, BK
SINGH, YP
BOHRA, R
SRIVASTAVA, G
RAI, AK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 444 (1-2) : 47 - 51

← 1 2 3 4 5 →