Palladium-Catalyzed Selective Dehydrogenative Cross-Couplings of Heteroarenes

被引：152
|
作者：
Bugaut, Xavier [1 ]
Glorius, Frank [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 33期
关键词：
biaryls; C-H bond activation; heterocycles; oxidative cross-coupling; palladium; DIRECT ARYLATION; PRECATALYST; MECHANISM; AZINE;
D O I：
10.1002/anie.201103106
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nice couple: Two heteroaryls bearing no prefunctionalization can be cross-coupled efficiently through Pd II catalysis to afford the biheteroaryl. The selectivity of this transformation probably finds its origin in the two mechanistically different metalation steps of Ci-H bonds. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：7479 / 7481
页数：3
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